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#1 Re: Quantum Chemistry » unrestricted wB97X-D and TPSSh functionals for paramagnetic species » 2024-03-16 04:34:22

How can I use unrestricted version of PBE0-D3(BJ), wB97x-D or TPSSh for paramagnetic radicals? Thanks a lot!

#2 Quantum Chemistry » unrestricted wB97X-D and TPSSh functionals for paramagnetic species » 2024-03-13 15:53:15

Majumder.21
Replies: 3

I want to explore an alkyl radical capture by a Ni(II) species and that would form Ni(III) complex which would eventually undergo C(sp3)-C(sp3) reductive elimination. I wanted to see how the optimized transition state would look like for those functionals (not single points) in gaussian16, except for the fact that I tried UB3LYP-D3 and UM06-D3 already. Any help would be appreciated.

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