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#2 Re: Multiwfn and wavefunction analysis » Error: Cannot found MOs in NAO basis in the input file » 2018-03-09 16:53:36

Thank you for your immediate response.
Your tutorial at http://sobereva.com/134 is useful in case of drawing the NBO orbitals, which is not what I want.
I will write in more detail my problem.

I want to find the contribution of each atomic orbital to the molecular orbitals through the orbital composition analysis by NAO method provided at Multiwfn.
I typed the three following commands (A, B and C) in the Linux terminal and received the following error:

A) ./Multiwfn P4S6CCSDfNBOread2.FChk
B) 8 (Orbital Composition Analysis)
C) 7 (Orbital composition analysis by natural atomic orbital (NAO) method)

Error: Cannot found MOs in NAO basis in the input file, the input file is invalid for this function! Please read manual carefully

This is close-shell calculation

-10 Return
-1 Define fragment (for option 1)
0 Show composition of an orbital
1 Show fragment contribution in a range of orbitals
2 Select output mode (for option 0), current: Only show core and valence NAOs

I would be grateful for any suggestion or help.
Also, you could download the file P4S6CCSDfNBOread2.FChk in this link https://we.tl/LGrjz0tcOO

Could it be a possible bug of the program?

Thank you for your time.

#3 Multiwfn and wavefunction analysis » Error: Cannot found MOs in NAO basis in the input file » 2018-03-09 09:55:49

msemidalas
Replies: 4

Dear all,

In the following input file, I want to perform NBO calculation and then an orbital decomposition analysis.
I get this error running Multiwf at the Test.Fchk:

Error: Cannot found MOs in NAO basis in the input file, the input file is invalid for this function! Please read the manual carefully
This is close-shell calculation

Here is my input file:

%chk=P4S6CCSDf.chk
%NProcShared=8
#P pbe1pbe/gen integral(grid=ultrafine) pseudo=read density=current pop=nboread formcheck

LanL08d

0 1
P,-1.2820354831,1.2820354831,1.2820354831
S,0.,0.,2.453134515
S,0.,2.453134515,0.
S,-2.453134515,0.,0.
P,1.2820354831,-1.2820354831,1.2820354831
S,2.453134515,0.,0.
P,1.2820354831,1.2820354831,-1.2820354831
S,0.,0.,-2.453134515
P,-1.2820354831,-1.2820354831,-1.2820354831
S,0.,-2.453134515,0.

P     0
S   1   1.00
      1.5160000              1.0000000       
S   1   1.00
      0.3369000              1.0000000       
S   1   1.00
      0.1211000              1.0000000       
P   1   1.00
      3.7050000              1.0000000       
P   1   1.00
      0.3934000              1.0000000       
P   1   1.00
      0.1190000              1.0000000       
P   1   1.00
      0.0298000              1.0000000       
D   1   1.00
      0.3640000              1.0000000       
****
S     0
S   1   1.00
      1.8500000              1.0000000       
S   1   1.00
      0.4035000              1.0000000       
S   1   1.00
      0.1438000              1.0000000       
P   1   1.00
      4.9450000              1.0000000       
P   1   1.00
      0.4870000              1.0000000       
P   1   1.00
      0.1379000              1.0000000       
P   1   1.00
      0.0347000              1.0000000       
D   1   1.00
      0.4960000              1.0000000       
****

P     0
P-ECP     2     10
d-ul potential
  5
1    462.1211423            -10.0000000       
2     93.6863701            -79.4864658       
2     21.2349094            -28.3668251       
2      6.3388415             -9.8577589       
2      2.0620684             -1.0163783       
s-ul potential
  5
0     78.0831823              3.0000000       
1     58.9576810             12.9104154       
2     36.0571255            150.0250298       
2     11.2464453             71.7083146       
2      2.6757561             23.0397012       
p-ul potential
  6
0     75.1617880              5.0000000       
1     57.4544041              6.3446507       
2     47.9481748            198.5585104       
2     18.4588360            111.1470820       
2      5.9414190             40.3944144       
2      1.8487507              6.4483233       
S     0
S-ECP     2     10
d-ul potential
  5
1    532.6685222            -10.0000000       
2    108.1342248            -85.3593846       
2     24.5697664            -30.4513290       
2      7.3702438            -10.3745886       
2      2.3712569             -0.9899295       
s-ul potential
  5
0    106.3176781              3.0000000       
1    100.8245833             10.6284036       
2     53.5858472            223.6360469       
2     15.3706332             93.6460845       
2      3.1778402             28.7609065       
p-ul potential
  6
0    101.9709185              5.0000000       
1     93.2808973              6.0969842       
2     65.1431772            285.4425500       
2     24.6347440            147.1448413       
2      7.8120535             53.6569778       
2      2.3112730              8.9249559       


$NBO NAOMO $END

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